Download latest version of ppsspp
for android here
Install and open ppsspp,
Goto settings>networking and set it like this :
Both the two phones should be set like this, the only difference is Mac address.
Goto setting>graphics and set it like this:
Exit ppsspp, open your mobile hotspot, ask your friend to connect.
Open ppsspp, load pes 2013
Goto setup room:
You should see this:
Ask your friend to goto match>adhoc and search for match room like this:
After some seconds he should see you in the room like this depending on the name you use, i use geoganer:
Ask him to click on your name.
After he click your screen will become like this:
Then goto next match:
Choose your teams:
And start playing: